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Effect of the Ruffled Porphyrin Ring on Electronic Structures: Structure and Characterization of [Fe(TalkylP)(OClO(3))] and [Fe(TPrP)(THF)(2)]ClO(4) (alkyl = Ethyl, Et and n-Propyl, Pr)
We report the synthesis of Fe(TalkylP)(OClO(3))] (alkyl = ethyl and propyl) and [Fe(TPrP)(THF)(2)]ClO(4), which are characterized by UV-vis, EPR, X-ray crystallography, and solid-state magnetic susceptibilities. The macrocycles of all three complexes are ruffled, all of the structural features for [...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3633537/ https://ncbi.nlm.nih.gov/pubmed/23626455 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1142/S1088424612501362 |
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