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Regio- and stereoselective carbometallation reactions of N-alkynylamides and sulfonamides

The carbocupration reactions of heterosubstituted alkynes allow the regio- and stereoselective formation of vinyl organometallic species. N-Alkynylamides (ynamides) are particularly useful substrates for the highly regioselective carbocupration reaction, as they lead to the stereodefined formation o...

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Detalhes bibliográficos
Main Authors: Minko, Yury, Pasco, Morgane, Chechik, Helena, Marek, Ilan
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3628878/
https://ncbi.nlm.nih.gov/pubmed/23616793
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.57
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