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Correlation of the rates of solvolysis of tert-butyl chlorothioformate and observations concerning the reaction mechanism

The “parent” tertiary alkyl chloroformate, tert-butyl chloroformate, is unstable, but the tert-butyl chlorothioformate (1) is of increased stability and a kinetic investigation of the solvolyses is presented. Analyses in terms of the simple and extended Grunwald-Winstein equations are carried out. T...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Kyong, Jin Burm, Lee, Yelin, D’Souza, Malcolm John, Kevill, Dennis Neil
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2012
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC3607629/
https://ncbi.nlm.nih.gov/pubmed/23538747
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.5155/eurjchem.3.3.267-272.624
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