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Correlation of the rates of solvolysis of tert-butyl chlorothioformate and observations concerning the reaction mechanism
The “parent” tertiary alkyl chloroformate, tert-butyl chloroformate, is unstable, but the tert-butyl chlorothioformate (1) is of increased stability and a kinetic investigation of the solvolyses is presented. Analyses in terms of the simple and extended Grunwald-Winstein equations are carried out. T...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2012
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3607629/ https://ncbi.nlm.nih.gov/pubmed/23538747 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.5155/eurjchem.3.3.267-272.624 |
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