The mixed-valent copper thiol­ate complex hexa­kis­{μ(3)-2-[(1,3-dimethyl­imidazol­idene)amino]­benzene­thiol­ato}dicopper(II)tetra­copper(I) bis­(hexa­fluoridophosphate) acetonitrile disolvate dichloro­methane disolvate

The mol­ecular structure of the title compound, [Cu(4) (I)Cu(2) (II)(C(11)H(14)N(3)S)(6)](PF(6))(2)·2CH(3)CN·2CH(2)Cl(2), shows a mixed-valent copper(I/II) thiol­ate complex with a distorted tetra­hedral coordination of the Cu(I) and Cu(II) cations by one guanidine N atom and three S atoms each. Cha...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Neuba, Adam, Flörke, Ulrich, Henkel, Gerald
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: International Union of Crystallography 2012
Gaiak:
Metal-Organic Papers
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC3588332/
https://ncbi.nlm.nih.gov/pubmed/23476349
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536812050428
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