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Dimensionality effects in the electronic structure of organic semiconductors consisting of polar repeat units

In conjugated organic molecules, excitation gaps typically decrease reciprocally with increasing the number of repeat units, n. This usually holds for individual molecules as well as for the corresponding bulk materials. Here, we show using density-functional theory calculations that a qualitatively...

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Hlavní autoři: Rissner, Ferdinand, Natan, Amir, Egger, David A., Hofmann, Oliver T., Kronik, Leeor, Zojer, Egbert
Médium: Artigo
Jazyk:Inglês
Vydáno: Elsevier Science 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3587343/
https://ncbi.nlm.nih.gov/pubmed/23470879
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.orgel.2012.09.003
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