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A Reinvestigation of the Dimer of para-Benzoquinone with Pyrimidine with MP2, CCSD(T) and DFT using Functionals including those Designed to Describe Dispersion

We reevaluate the interaction of pyridine and p-benzoquinone using functionals designed to treat dispersion. We compare the relative energies of four different structures: stacked, T-shaped (identified for the first time) and two planar H-bonded geometries using these functionals (B97-D, ωB97x-D, M0...

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Detalhes bibliográficos
Main Authors: Marianski, Mateusz, Oliva, Antoni, Dannenberg, J. J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3586993/
https://ncbi.nlm.nih.gov/pubmed/22765283
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp3050274
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