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Stereoretentive Chlorination of Cyclic Alcohols Catalyzed by Titanium (IV) Tetrachloride: Evidence for a Front Side Attack Mechanism
A mild chlorination reaction of alcohols was developed using the classical thionyl chloride reagent but with added catalytic titanium (IV) chloride. These reactions proceeded rapidly to afford chlorination products in excellent yields and with preference for retention of configuration. Stereoselecti...
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| Hauptverfasser: | , , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3586301/ https://ncbi.nlm.nih.gov/pubmed/23298402 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo3023439 |
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