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Energetics and Dynamics of the Low-Lying Electronic States of Constrained Polyenes: Implications for Infinite Polyenes

Steady-state and ultrafast transient absorption spectra were obtained for a series of conformationally-constrained, isomerically pure polyenes with 5–23 conjugated double bonds (N). These data and fluorescence spectra of the shorter polyenes reveal the N dependence of the energies of six (1)B(u)(+)...

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Autors principals: Christensen, Ronald L., Enriquez, Miriam M., Wagner, Nicole L., Peacock-Villada, Alexandra Y., Scriban, Corina, Schrock, Richard R., Polívka, Tomáš, Frank, Harry A., Birge, Robert R.
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3584643/
https://ncbi.nlm.nih.gov/pubmed/23330819
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp310592s
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