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Cross-Strand Interactions of Fluorinated Amino Acids in β-Hairpin Constructs
We describe here the design, synthesis and thermodynamic characterization of fluorinated β-hairpin constructs. Introduction of hexafluoroleucine (Hfl) did not perturb β-hairpin formation, as judged by (1)H NMR structures of four peptides determined to <1 Å backbone RMSDs, allowing direct comparis...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3574618/ https://ncbi.nlm.nih.gov/pubmed/23078597 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja212080f |
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