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Transition Metal Photoredox Catalysis of Radical Thiol-Ene Reactions
[Image: see text] We describe the anti-Markovnikov hydrothiolation of olefins using visible light absorbing transition metal photocatalysts. The key thiyl radical intermediates are generated upon quenching of photoexcited Ru*(bpz)(3)(2) with a variety of thiols. The adducts of a wide variety of olef...
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| 主要な著者: | , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2012
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3573243/ https://ncbi.nlm.nih.gov/pubmed/23094660 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo3020825 |
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