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Transition Metal Photoredox Catalysis of Radical Thiol-Ene Reactions

[Image: see text] We describe the anti-Markovnikov hydrothiolation of olefins using visible light absorbing transition metal photocatalysts. The key thiyl radical intermediates are generated upon quenching of photoexcited Ru*(bpz)(3)(2) with a variety of thiols. The adducts of a wide variety of olef...

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書誌詳細
主要な著者: Tyson, Elizabeth L., Ament, Michael S., Yoon, Tehshik P.
フォーマット: Artigo
言語:Inglês
出版事項: 2012
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3573243/
https://ncbi.nlm.nih.gov/pubmed/23094660
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo3020825
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