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A new synthetic access to 2-N-(glycosyl)thiosemicarbazides from 3-N-(glycosyl)oxadiazolinethiones and the regioselectivity of the glycosylation of their oxadiazolinethione precursors

Glycosylations of 5-(1H-indol-2-yl)-1,3,4-oxadiazoline-2(3H)-thione delivered various degrees of S- and/or N-glycosides depending on the reaction conditions. S-Glycosides were obtained regiospecifically by grinding oxadiazolinethiones with acylated α-D-glycosyl halides in basic alumina, whereas 3-N-...

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Detalhes bibliográficos
Main Authors: El Ashry, El Sayed H, El Tamany, El Sayed H, Fattah, Mohy El Din Abdel, Aly, Mohamed R E, Boraei, Ahmed T A, Duerkop, Axel
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3566832/
https://ncbi.nlm.nih.gov/pubmed/23400104
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.16
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