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Simplifying Nickel(0) Catalysis: An Air-stable, COD-free Nickel Precatalyst for the Internally-selective Benzylation of Terminal Alkenes

The synthesis and characterization of the air-stable nickel(II) complex trans-(PCy(2)Ph)(2)Ni(o-tolyl)Cl is described in conjunction with an investigation of its use for Mizoroki Heck-type, room temperature, internally-selective coupling of substituted benzyl chlorides with terminal alkenes. This re...

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Detalhes bibliográficos
Main Authors: Standley, Eric A., Jamison, Timothy F.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3564234/
https://ncbi.nlm.nih.gov/pubmed/23316879
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3116718
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