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Synthesis and Characterization of a Novel Diels – Alder Adduct of Codeine
The Diels – Alder reaction was applied to 4,5-epoxymorphinan opioids to generate a novel aromatic cycloadduct at C(7) – C(8): Thermolytic cleavage of sultine 8 produced the reactive diene o-quinodimethane 7 which condensed favorably with codeine (11), but not with codeinone (9) or 14- hydroxycodeino...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3562130/ https://ncbi.nlm.nih.gov/pubmed/23378668 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/hlca.200900234 |
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