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X-ray Spectroscopic Observation of an Interstitial Carbide in NifEN-bound FeMoco Precursor
The iron-molybdenum cofactor (FeMoco) of nitrogenase contains a biologically unprecedented μ(6)-coordinated C(4−) ion. Although the role of this interstitial atom in nitrogenase catalysis is unknown, progress has been made on understanding its biosynthetic origins. Here, we report valence-to-core (V...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2013
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3555700/ https://ncbi.nlm.nih.gov/pubmed/23276198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309254g |
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