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D-Glucosamine-Derived Synthons for Assembly of L-threo-Sphingoid Bases. Total Synthesis of Rhizochalinin C
A five-step transformation of D-glucosamine – commencing with indium-mediated Barbier reaction, without isolation of intermediates – into (R,R)-2-aminohex-5-en-1,3-diol is described. The latter is a useful synthon for assembly of L-threo-sphingoid bases; long-chain aminoalkanols and aminoalkanediols...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3548972/ https://ncbi.nlm.nih.gov/pubmed/23227909 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo302355t |
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