Restricted Photochemistry in the Molecular Solid State: Structural changes on Photoexcitation of Cu(I) Phenanthroline metal-to-ligand-charge-transfer (MLCT) complexes by Time-Resolved Diffraction

The excited state structure of [Cu(1)[(1,10-phenanthroline-N,N’) bis(triphenylphosphine)] cations in their crystalline [BF(4)] salt has been determined at both 180 and 90K by single-pulse time-resolved synchrotron experiments with the modified polychromatic Laue method. The two independent molecules...

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Main Authors: Makal, Anna, Benedict, Jason, Trzop, Elzbieta, Sokolow, Jesse, Fournier, Bertrand, Chen, Yang, Kalinowski, Jarosław A., Graber, Tim, Henning, Robert, Coppens, Philip
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3545449/
https://ncbi.nlm.nih.gov/pubmed/22385365
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp300313s
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