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Facially Selective Cu-catalyzed Carbozincation of Cyclopropenes Using Arylzinc Reagents Formed by Sequential I/Mg/Zn exchange

[Image: see text] Described is a Cu-catalyzed directed carbozincation of cyclopropenes with organozinc reagents prepared by I/Mg/Zn exchange. This protocol broadens the scope with respect to functional group tolerance and enables use of aryl iodide precursors, rather than purified diorganozinc precu...

詳細記述

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書誌詳細
主要な著者: Tarwade, Vinod, Selvaraj, Ramajeyam, Fox, Joseph M.
フォーマット: Artigo
言語:Inglês
出版事項: 2012
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3538081/
https://ncbi.nlm.nih.gov/pubmed/23035947
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo3019076
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