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Coupling Coherence Distinguishes Structure Sensitivity in Protein Electron Transfer

Quantum mechanical analysis of electron tunneling in nine thermally fluctuating cytochrome b(562) derivatives reveals two distinct protein-mediated coupling limits. A structure-insensitive regime arises for redox partners coupled through dynamically averaged multiple-coupling pathways (in seven of t...

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Detalhes bibliográficos
Main Authors: Prytkova, Tatiana R., Kurnikov, Igor V., Beratan, David N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3523119/
https://ncbi.nlm.nih.gov/pubmed/17272715
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1134862
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