Llwytho...

Experimental Documentation of the Structural Consequences of Hydrogen-Bonding Interactions to the Proximal Cysteine of a Cytochrome P450()

Resonance Raman spectroscopy is used to document, for the first time, a 6 cm(−1) decrease of the Fe-S stretch by introducing an H-bond donor into the proximal pocket of a cytochrome P450, which interacts with the key cysteine thiolate axial ligand. The anticipated trans-effect on bound exogenous lig...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Mak, Piotr J., Yang, Yuting, Im, Sangchoul, Waskell, Lucy A., Kincaid, James R.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2012
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3517159/
https://ncbi.nlm.nih.gov/pubmed/22968976
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201205912
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