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A Benchmark Test Suite for Proton Transfer Energies and its Use to Test Electronic Structure Model Chemistries

We present benchmark calculations of nine selected points on potential energy surfaces describing proton transfer process in three model systems, H(5)O(2)(+), CH(3)OH…H(+)…OH(2), and CH(3)COOH…OH(2). The calculated relative energies of these geometries are compared to those calculated by various wav...

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Hlavní autoři: Nachimuthu, Santhanamoorthi, Gao, Jiali, Truhlar, Donald G
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3516617/
https://ncbi.nlm.nih.gov/pubmed/23230346
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chemphys.2012.01.014
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