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Reactivity ratios, and mechanistic insight for anionic ring-opening copolymerization of epoxides

Reactivity ratios were evaluated for anionic ring-opening copolymerizations of ethylene oxide (EO) with either allyl glycidyl ether (AGE) or ethylene glycol vinyl glycidyl ether (EGVGE) using a benzyl alkoxide initiator. The chemical shift for the benzylic protons of the initiator, as measured by (1...

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Detalhes bibliográficos
Main Authors: Lee, Bongjae F., Wolffs, Martin, Delaney, Kris T., Sprafke, Johannes K., Leibfarth, Frank A., Hawker, Craig J., Lynd, Nathaniel A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3514019/
https://ncbi.nlm.nih.gov/pubmed/23226879
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma300634d
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