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Influence of intramolecular hydrogen bonds on the binding potential of methylated β-cyclodextrin derivatives
Various heptasubstituted derivatives of β-cyclodextrin (β-CD) bearing 1, 2 and 3 methyl substituents per glucose unit were synthesized by regioselective methods. Binding free energies and binding enthalpies of these hosts towards 4-tert-butylbenzoate and adamantane-1-carboxylate were determined by i...
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| Natura: | Artigo |
| Lingua: | Inglês |
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Beilstein-Institut
2012
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3511027/ https://ncbi.nlm.nih.gov/pubmed/23209527 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.218 |
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