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Synthesis of Oximidine II Via a Cu-Mediated Reductive Ene-Yne Macrocyclization
An intramolecular copper-mediated reductive Castro-Stephens reaction furnished a key macrocyclic triene intermediate for the total synthesis of oximidine II. Herein we describe the total synthesis of the natural product as well as studies to deduce the mechanism of this unprecedented reaction.
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2011
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3505758/ https://ncbi.nlm.nih.gov/pubmed/21717556 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201103081 |
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