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Trimethyl lock: A trigger for molecular release in chemistry, biology, and pharmacology
The trimethyl lock is an o-hydroxydihydrocinnamic acid derivative in which unfavorable steric interactions between three pendant methyl groups encourage lactonization to form a hydrocoumarin. This reaction is extremely rapid, even when the electrophile is an amide and the leaving group is an amino g...
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| Hauptverfasser: | , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3501758/ https://ncbi.nlm.nih.gov/pubmed/23181187 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC20536J |
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