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Reversible Binding of Nitric Oxide to an Fe(III) Complex of a Tetra-amido Macrocycle
Nitric oxide binds reversibly to the Fe(III) complex of a well-developed tetra-amido macrocyclic ligand. Reaction with NO results in formation of a species consistent with an S=1 {Fe-NO}(6) ground state as characterized by UV-vis, IR, EPR, and Mössbauer spectroscopy. The resultant nitrosyl is labile...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3500910/ https://ncbi.nlm.nih.gov/pubmed/23133836 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2cc37221e |
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