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Relationship between transfer activity coefficients, (S(1))γ(S(2)), of cryptate 2.2.2 complexes and their stability constant in various solvents

Between dipolar aprotic solvents S(1) and S(2), the transfer activity coefficients, (S(1))γ(S(2)), of complexed sodium, potassium, thallium(I), and silver ions with cryptand 2.2.2 have been found to be equal to that of the cryptand. With reference to methanol (S(1)), this equality does not hold, the...

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Hlavní autoři: Kolthoff, Izaak M., Chantooni, Miran K.
Médium: Artigo
Jazyk:Inglês
Vydáno: 1980
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC349989/
https://ncbi.nlm.nih.gov/pubmed/16592871
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