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(13)C and (199)Hg nuclear magnetic resonance spectroscopic study of alkenemercurinium ions: Effect of methyl substituents on (199)Hg chemical shifts

The long-lived ethylene, cyclohexene, and norbornenemercurinium ions prepared in superacidic, low-nucleophilic media have been studied by (13)C and (199)Hg NMR spectroscopy. The norbornenemercurinium ion shows temperature-dependent (13)C and (199)Hg NMR spectra, consistent with equilibration via rap...

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Detalhes bibliográficos
Main Authors: Olah, George A., Garcia-Luna, Armando
Formato: Artigo
Idioma:Inglês
Publicado em: 1980
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC349988/
https://ncbi.nlm.nih.gov/pubmed/16592870
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