Vibrational Probes and Determinants of the S = 0 ⇌ S = 2 Spin Crossover in Five-Coordinate [Fe(TPP)(CN)](−)

The low-frequency vibrational characterization of the spin crossover complex, five-coordinate cyano(tetraphenylporpyrinato)iron(II), [Fe(TPP)(CN)](−), is reported. Nuclear resonance vibrational spectroscopy has been used to measure all low-frequency vibrations involving iron at several temperatures;...

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Hauptverfasser: Li, Jianfeng, Peng, Qian, Barabanschikov, Alexander, Pavlik, Jeffrey W., Alp, E. Ercan, Sturhahn, Wolfgang, Zhao, Jiyong, Sage, J. Timothy, Scheidt, W. Robert
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2012
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3498855/
https://ncbi.nlm.nih.gov/pubmed/23082814
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301719v
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