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Baeyer-Villiger C-C bond cleavage reaction in gilvocarcin and jadomycin biosynthesis
GilOII has been unambiguously identified as the key enzyme performing the crucial C-C bond cleavage reaction responsible for the unique rearrangement of a benz[a]anthracene skeleton to the benzo[d]naphthopyranone backbone typical for the gilvocarcin type natural anticancer antibiotics. Further inves...
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| Main Authors: | , , , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3498853/ https://ncbi.nlm.nih.gov/pubmed/23102024 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3081154 |
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