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Baeyer-Villiger C-C bond cleavage reaction in gilvocarcin and jadomycin biosynthesis

GilOII has been unambiguously identified as the key enzyme performing the crucial C-C bond cleavage reaction responsible for the unique rearrangement of a benz[a]anthracene skeleton to the benzo[d]naphthopyranone backbone typical for the gilvocarcin type natural anticancer antibiotics. Further inves...

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Bibliografische gegevens
Hoofdauteurs: Tibrewal, Nidhi, Pahari, Pallab, Wang, Guojun, Kharel, Madan K., Morris, Caleb, Downey, Theresa, Hou, Yanpeng, Bugni, Tim S., Rohr, Jürgen
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2012
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3498853/
https://ncbi.nlm.nih.gov/pubmed/23102024
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3081154
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