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Palladium-Catalyzed Diastereo- and Enantioselective Formal [3+2]-Cycloadditions of Substituted Vinylcyclopropanes
We describe a palladium-catalyzed diastereo- and enantioselective formal [3+2]-cycloaddition between substituted vinyl-cyclopropanes and electron deficient olefins in the form of azlactone- and Meldrum’s acid alkylidenes to give highly-substituted cyclo-pentane products. By modulation of the electro...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2012
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3495600/ https://ncbi.nlm.nih.gov/pubmed/23030714 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309003x |
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