A Mononuclear Fe(III) Single Molecule Magnet with a 3/2↔5/2 Spin Crossover

The air stable complex [(PNP)FeCl(2)] (1) (PNP = N[2-P(CHMe(2))(2)-4-methylphenyl](2)(−)), prepared from one-electron oxidation of [(PNP)FeCl] with ClCPh(3), displays an unusual S = 3/2 to S = 5/2 transition above 80 K as inferred by the dc SQUID magnetic susceptibility measurement. The ac SQUID mag...

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Detalhes bibliográficos
Main Authors: Mossin, Susanne, Tran, Ba L., Adhikari, Debashis, Pink, Maren, Heinemann, Frank W., Sutter, Jörg, Szilagyi, Robert K., Meyer, Karsten, Mindiola, Daniel J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3495239/
https://ncbi.nlm.nih.gov/pubmed/22817325
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja302660k
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