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A Universal Scaffold for Synthesis of the Fe(CN)(2)(CO) Moiety of [NiFe] Hydrogenase
Hydrogen-cycling [NiFe] hydrogenases harbor a dinuclear catalytic center composed of nickel and iron ions, which are coordinated by four cysteine residues. Three unusual diatomic ligands in the form of two cyanides (CN(−)) and one carbon monoxide (CO) are bound to the iron and apparently account for...
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| Auteurs principaux: | , , , , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
American Society for Biochemistry and Molecular Biology
2012
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3493926/ https://ncbi.nlm.nih.gov/pubmed/23019332 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M112.376947 |
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