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Iridium-Catalyzed Regioselective and Enantioselective Allylation of Trimethylsiloxyfuran
We report the regioselective and enantioselective allylation of an ester enolate, trimethylsiloxyfuran. This enolate reacts in the 3-position with linear aromatic allylic carbonates or aliphatic allylic benzoates to form the branched substitution products in the presence of a metallacyclic iridium c...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2012
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3487469/ https://ncbi.nlm.nih.gov/pubmed/22954355 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja306850b |
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