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Metal Controlled Diastereoselective Self-assembly and Circularly Polarized Luminescence of a Chiral Heptanuclear Europium Wheel

The chiral dissymmetric tetradentate ligand SPhbipox (6’-(4-phenyloxazolin-2-yl)-2,2’-bipyridine-6-carboxylic acid) leads to the diastereoselective assembly of a homochiral Eu(III) triangle and of a highly emissive (QY=27%) heptanuclear wheel which is the largest example of chiral luminescent comple...

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Detalhes bibliográficos
Main Authors: Bozoklu, Gülay, Gateau, Christelle, Imbert, Daniel, Pécaut, Jacques, Robeyns, Koen, Filinchuk, Yaroslav, Memon, Farah, Muller, Gilles, Mazzanti, Marinella
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3478891/
https://ncbi.nlm.nih.gov/pubmed/22548280
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3020814
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