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Appropriate constraints for variational optimization of electronic density matrices and electron densities

Euler equations characteristic of the electronic reduced density matrix have previously been obtained by minimizing an energy functional subject to trace constraints 〈P(K)〉 = N, in which N is the number of particles. It is shown that these constraints are inadequate to exclude variations that violat...

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Hlavní autor: Payne, Philip W.
Médium: Artigo
Jazyk:Inglês
Vydáno: 1982
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC347129/
https://ncbi.nlm.nih.gov/pubmed/16593242
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