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A GGA+U approach to effective electronic correlations in thiolate-ligated iron-oxo (IV) porphyrin

High-valent oxo-metal complexes exhibit correlated electronic behavior on dense, low-lying electronic state manifolds, presenting challenging systems for electronic structure methods. Among these species, the iron-oxo (IV) porphyrin denoted Compound I occupies a privileged position, serving a broad...

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Bibliografiset tiedot
Päätekijät: Elenewski, Justin E., Hackett, John C
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: American Institute of Physics 2012
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC3470609/
https://ncbi.nlm.nih.gov/pubmed/23020335
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4755290
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