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(2.2.2-Cryptand)potassium tetrakis(η(2)-ethylene)cobaltate(−I)
The title salt, [K(C(18)H(36)N(2)O(6))][Co(C(2)H(4))(4)], is one of only two known homoleptic ethylenemetalates. The cation and anion are well separated, which gives an unperturbed tetrahedral anion as is expected for a formally Co(−I) d (10) metal center. The considerable elongation of the C=C bo...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
International Union of Crystallography
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3470144/ https://ncbi.nlm.nih.gov/pubmed/23125588 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536812038287 |
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