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(18)O isotope shift in (15)N NMR analysis of biological N-oxidations: H(2)O-NO(2)(-) exchange in the ammonia-oxidizing bacterium Nitrosomonas
The (18)O/(16)O shifts in (15)N NMR were determined for nitrite (0.13 ppm or 4.2 Hz at 7.05 T) and nitrate (0.056 ppm or 1.7 Hz at 7.05 T) at neutral pH. The technique, which allows clear differentiation between (16)O and (18)O derivatives of (15)N, was used to assess the source of oxygens in nitrit...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
1982
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC347012/ https://ncbi.nlm.nih.gov/pubmed/16593233 |
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