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A Single UV or Near IR Triggering Event Leads to Polymer Degradation into Small Molecules

We report two polymers with UV- and NIR-removable end caps that respond to a single light activated event by complete cleavage of the polymer backbone via a self-immolative mechanism. Two photocleavable protecting groups were used to cap the polymers; o-nitrobenzyl alcohol (ONB) and bromo-coumarin (...

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Hlavní autoři: de Gracia Lux, Caroline, McFearin, Cathryn L., Joshi-Barr, Shivanjali, Sankaranarayanan, Jagadis, Fomina, Nadezda, Almutairi, Adah
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3467153/
https://ncbi.nlm.nih.gov/pubmed/23066523
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/mz3002403
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