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Crotylboron-Based Synthesis of the Polypropionate Units of Chaxamycins A/D, Salinisporamycin, and Rifamycin S
Syntheses of the C(15)–C(27) fragments of chaxamycins A/D, rifamycin S, and the C(12)–C(24) fragment of salinisporamycin have been accomplished in ten steps from commercially available starting materials. Three crotylboron reagents were utilized to construct the seven contiguous stereocenters in the...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3465507/ https://ncbi.nlm.nih.gov/pubmed/22703288 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo3008226 |
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