Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO

The effective design of an artificial photosynthetic system entails the optimization of several important interactions. Herein we report stopped-flow UV-visible (UV-vis) spectroscopy, X-ray crystallographic, density functional theory (DFT), and electrochemical kinetic studies of the Re(bipy-tBu)(CO)...

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Main Authors: Smieja, Jonathan M., Benson, Eric E., Kumar, Bhupendra, Grice, Kyle A., Seu, Candace S., Miller, Alexander J. M., Mayer, James M., Kubiak, Clifford P.
Format: Artigo
Jezik:Inglês
Izdano: National Academy of Sciences 2012
Teme:
Chemical Approaches to Artificial Photosynthesis: Solar Fuels Special Feature
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3465436/
https://ncbi.nlm.nih.gov/pubmed/22652573
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1119863109
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