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Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO

The effective design of an artificial photosynthetic system entails the optimization of several important interactions. Herein we report stopped-flow UV-visible (UV-vis) spectroscopy, X-ray crystallographic, density functional theory (DFT), and electrochemical kinetic studies of the Re(bipy-tBu)(CO)...

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Detalhes bibliográficos
Main Authors: Smieja, Jonathan M., Benson, Eric E., Kumar, Bhupendra, Grice, Kyle A., Seu, Candace S., Miller, Alexander J. M., Mayer, James M., Kubiak, Clifford P.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2012
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3465436/
https://ncbi.nlm.nih.gov/pubmed/22652573
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1119863109
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