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Ab initio calculations of dilithiopropenes

Ab initio molecular orbital calculations with the 3-21G basis set show the most stable dilithiopropene structure to be the di-π lithium-bridged structure VI of 1,3-dilithiopropene. This structure is most simply regarded as an ion triplet of two lithium cations and a propenylidene dianion.

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Kost, Daniel, Klein, Joseph, Streitwieser, Andrew, Schriver, George W.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 1982
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC346543/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16593203/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.79.12.3922
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