Mimicking the electron transfer chain in photosystem II with a molecular triad thermodynamically capable of water oxidation

In the photosynthetic photosystem II, electrons are transferred from the manganese-containing oxygen evolving complex (OEC) to the oxidized primary electron-donor chlorophyll P680(•+) by a proton-coupled electron transfer process involving a tyrosine-histidine pair. Proton transfer from the tyrosine...

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Detalhes bibliográficos
Main Authors: Megiatto, Jackson D., Antoniuk-Pablant, Antaeres, Sherman, Benjamin D., Kodis, Gerdenis, Gervaldo, Miguel, Moore, Thomas A., Moore, Ana L., Gust, Devens
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2012
Assuntos:
Chemical Approaches to Artificial Photosynthesis: Solar Fuels Special Feature
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3465380/
https://ncbi.nlm.nih.gov/pubmed/22566659
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1118348109
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