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Site-isolated redox reactivity in a trinuclear iron complex
The symmetric, high-spin triiron complex ((Ph)L)Fe(3)(thf)(3) reacts with mild chemical oxidants (e.g., Ph(3)CX, I(2)) to afford an asymmetric core where one iron ion bears the halide ligand ((Ph)L)Fe(3)X(L), and the hexadentate ((Ph)L = MeC(CH(2)NPh-o-NPh)(3)) ligand has undergone significant rearr...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3464975/ https://ncbi.nlm.nih.gov/pubmed/22988949 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301241s |
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