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Temperature dependence of the reduction potential of blue copper in fungal laccase

Thin-layer spectroelectrochemical methods have been employed to measure the reduction potentials of the blue copper in Polyporus versicolor laccase (EC 1.10.3.2) between 7°C and 41°C (0.2 M sodium phosphate, pH 5.4). Thermodynamic parameters are: ΔS° = -13.9 ± 2 cal/mol-K; ΔH° = -22.1 ± 0.5 kcal/mol...

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Main Authors: Taniguchi, Vernon T., Malmström, Bo G., Anson, Fred C., Gray, Harry B.
Formato: Artigo
Idioma:Inglês
Publicado: 1982
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC346421/
https://ncbi.nlm.nih.gov/pubmed/16593193
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