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Nitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp(3)-C–H Bonds
This paper describes a new method for the catalytic aerobic oxygenation of unactivated sp(3)-C–H bonds. This transformation utilizes Pd(OAc)(2) as a catalyst in conjunction with NaNO(3) as a redox co-catalyst. Both oxime ether and pyridine derivatives are effective directing groups for these reactio...
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| Main Authors: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2012
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3462469/ https://ncbi.nlm.nih.gov/pubmed/23050075 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC20800H |
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