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Nitrate as a Redox Co-Catalyst for the Aerobic Pd-Catalyzed Oxidation of Unactivated sp(3)-C–H Bonds

This paper describes a new method for the catalytic aerobic oxygenation of unactivated sp(3)-C–H bonds. This transformation utilizes Pd(OAc)(2) as a catalyst in conjunction with NaNO(3) as a redox co-catalyst. Both oxime ether and pyridine derivatives are effective directing groups for these reactio...

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Autors principals: Stowers, Kara J., Kubota, Asako, Sanford, Melanie S.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3462469/
https://ncbi.nlm.nih.gov/pubmed/23050075
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C2SC20800H
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