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A quantitative approach to nucleophilic organocatalysis
The key steps in most organocatalytic cyclizations are the reactions of electrophiles with nucleophiles. Their rates can be calculated by the linear free-energy relationship log k(20 °C) = s(N)(E + N), where electrophiles are characterized by one parameter (E) and nucleophiles are characterized by t...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3458771/ https://ncbi.nlm.nih.gov/pubmed/23019481 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.166 |
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