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Neutral Nazarov-Type Cyclization Catalyzed by Pd(0)

[Image: see text] The first Pd(0)-catalyzed Nazarov-type cyclization of diketoesters proceeds in 70% to 95% yield under strictly neutral conditions. Aryl substitution is not required so the reaction succeeds with aliphatic substrates. The mechanism appears to be novel. A single asymmetric version of...

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Detalhes bibliográficos
Main Authors: Shimada, Naoyuki, Stewart, Craig, Bow, William F., Jolit, Anais, Wong, Kahoano, Zhou, Zhe, Tius, Marcus A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3445627/
https://ncbi.nlm.nih.gov/pubmed/22539448
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201201724
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